Preheat oven to 350°F and line the bottoms of three 6” cake pans with a round of parchment paper. Set aside.
In a medium bowl, stir together flour, cocoa powder, baking soda, baking powder, and salt. Set aside.
In a large mixing bowl, whisk together melted butter, oil, granulated sugar, and brown sugar, and eggs until combined.
Add half of the flour mixture to the butter mixture and whisk together until just combined.
In a measuring cup, add in the orange juice, orange zest, and milk. Pour half of this orange juice mixture into the batter and whisk until just combined.
Add in the remaining flour mixture and then the orange juice mixture, whisking in between additions until just combined and the batter is smooth and glossy.
Divide the batter into your three lined cake pans until about ⅓ full (I portioned out about 360g of batter into each pan).
Bake cakes for 35-40 minutes or until a toothpick inserted in the middle comes out clean.
Let cakes cool in the pans for 10-15 minutes or until cool enough to handle. Run a knife around the edges of the cake pan. Invert the cake pans to release the cake layers onto a wire rack or parchment paper and let them cool completely while upside down before assembling cake.